Rotational energy transfer viewed in the time domain by femtosecond CARSFemtosecond time-resolved coherent anti-Stokes Raman scattering (fs-CARS) provides a powerful tool for the investigation of collision-induced line broadening and mixing effects, e.g. for the validation of rotational energy transfer (RET) models. Whereas the linewidth determination with frequency resolved CARS is limited to the pressure range, where line mixing effects are negligible (typically <0.5 amagat for nitrogen), the time domain CARS signal becomes increasingly sensitive to the off-diagonal elements of the RET matrix at higher pressure (see figure below) [1]. The application of fs-CARS has very recently led to a new scaling law proposed for rotationally inelastic collisions, the angular momentum and energy corrected sudden approximation (AECS) [4,5].
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